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Satish Lele
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Vegetable Oils
Potential Specifications for Jatropha Curcas Oil to be converted into Bio Diesel.
FFA (preferably) : < 2.0% w/wWater content : < 1,000 ppm
Phosphorus : < 20 ppm w/wSulphur : < 50 ppm
Iodine Value (mg I2/100g) : < 120Saponification Number : >: 190 (mg KOH/g)
Specific Gravity : 0.840 to 0.920
Fatty Acid Profile
Myristic Acid : 0.38 %Palmitic Acid : 16.0 % max.
Palmitoleic Acid : 1 to 3.5 %Stearic Acid : 6 to 7.0 %
Oleic Acid : 42 to 43.5 %Linoleic Acid : 33 to 34.4 %
Linolenic Acid : >0.80 %Arachidic Acid : 0.20 %
Gadoleic Acid : 0.12 %

Jatropha oil is hydroscopic. Jatropha oil absorbs water and needs nitrogen blanketing in steel tanks. We are learning more and more about the properties of Jatropha. One issue that is quite clear is that, because Jatropha is high in acid, Jatropha oil has the tendency to degrade quickly, particularly if not handled properly through the supply chain.
Right from the time of expelling, the oil needs to be kept in storage conditions that prevent undue degradation. Exposure to air and moisture must be minimized, hence the need for nitrogen blanket in the tanks.
The range of fatty acids present in various seeds will differ but the oil and biodiesel that is produced must be acceptable. However, this assumes that oil is fully degummed. The degumming may well be more of a problem than making biodiesel!
The phospholipid, protein and phorbol ester contents in edible Jatropha seem to be quite different to non-edible. It needs to determined if this affects the degumming method. The degumming removes lecithin and other related compounds, so if these are high, then a modified degumming method may be needed.
If the oil is properly dried after degumming and kept under nitrogen blanketing. This may suffice. Bio diesel companies are investigating storage requirements and oxidative stability of Jatropha.
Seeds degrade as soon as they are picked and so careful storage and handling is required. In the warm humid atmosphere, the degradation of seeds can be rapid. Even in the cold countries, seeds storage is a problem. Recently an importer had samples of rape seeds, that had been harvested and stored in wet weather. The analysis showed that they had 28% of free fatty acid! They had a strong smell from the yeasts that were growing on the seeds.
Hence at temperature of >30oC the problems can be greater. Since the JC seeds are toxic, attack by animals and rodents is unlikely to be a problem.
Rubber Nitrile tanks are perfect for container shipping, as there is no exposure to the atmosphere or the air, this is because it is collapsible and always works in a vacuum. These can be fitted in a 20 feet, 30 ton container. Each container would hold about 22.4 tons Jatropha Curcas crude oil. Indian suppliers of these rubber tanks have been identified.

Oil yields and characteristics
Production of Fatty Oils
: These are conservative estimates, crop yields can vary widely.
Crop kg oil/ha liters oil/ha lbs oil/acre US gal/acre
corn (maize) 145 172 129  18
cashew nut 148 176 132  19
oats 183 217 163  23
lupine 195 232 175  25
kenaf 230 273 205  29
calendula 256 305 229  33
cotton 273 325 244  35
hemp 305 363 272  39
soybean 375 446 335  48
coffee 386 459 345  49
linseed (flax) 402 478 359  51
hazelnuts 405 482 362  51
euphorbia 440 524 393  56
pumpkin seed 449 534 401  57
coriander 450 536 402  57
mustard seed 481 572 430  61
camelina 490 583 438  62
sesame 585 696 522  74
safflower 655 779 585  83
rice 696 828 622  88
tung oil tree 790 940 705 100
sunflowers 800 952 714 102
cocoa (cacao)  863 1026  771  110
peanuts  890 1059  795  113
opium poppy  978 1163  873  124
rapeseed 1000 1190  893  127
olives 1019 1212  910  129
castor beans 1188 1413 1061  151
pecan nuts 1505 1791 1344  191
jojoba 1528 1818 1365  194
jatropha 1590 1892 1420  202
macadamia nuts 1887 2246 1685  240
brazil nuts 2010 2392 1795  255
avocado 2217 2638 1980  282
coconut 2260 2689 2018  287
oil palm 5000 5950 4465  635

Biodiesel yield = oil yield x 0.95 (approx.)
Oils and (BioDiesel) Esters Characteristics
Type of Oil Melting Range oC Iodine Number Cetane Number
Oil / Fat Methyl Ester Ethyl Ester
Rapeseed oil, h. eruc. 5 0 -2 97 to 105 55
Rapeseed oil, i. eruc. -5 -10 -12 110 to 115 58
Sunflower oil -18 -12 -14 125 to 135 52
Olive oil -12 -6 -8 77 to 94 60
Soybean oil -12 -10 -12 125 to 140 53
Cotton seed oil 0 -5 -8 100 to 115 55
Corn oil -5 -10 -12 115 to 124 53
Coconut oil 20 to 24 -9 -6 8 to 10 70
Palm kernel oil 20 to 26 -8 -8 12 to 18 70
Palm oil 30 to 38 14 10 44 to 58 65
Palm oleine 20 to 25 5 3 85 to 95 65
Palm stearine 35 to 40 21 18 20 to 45 85
Tallow 35 to 40 16 12 50 to 60 75
Lard 32 to 36 14 10 60 to 70 65


Fatty Acids contents of different oils

Fats and oils
Fatty acids %
C4:0
Butyric
C6:0
Caproic
C8:0
Caprylic
C10:0
Capric
C12:0
Lauric
C14:0
Myristic
C16:0
Palmitic
C16:1
Palmitoleic
Molecular wt.
88
116
144
172
200
228
256
254
Tallow
-
-
-
-
0.2
3
27
2
Lard
-
-
-
-
-
1
26
2
Butter
3.5
1.5
-
2.5
3
11
30
3.5
Coconut
-
-
8
8
48
16
8.5
-
Palm kernel
-
-
3
5
48.5
17
7.5
0.5
Palm
-
-
-
-
-
3.5
39.5
-
Safflower
-
-
-
-
-
-
5.2
-
Peanut
-
-
-
-
-
0.5
7
1.5
Cottonseed
-
-
-
-
-
1.5
19
-
Maize
-
-
-
-
-
1
9
1.5
Olive
-
-
-
-
0.5
1
13
2
Sunflower
-
-
-
-
-
-
6
-
Soy
-
-
-
-
-
0.3
7.8
0.4
Rapeseed/Canola
-
-
-
-
-
-
3.5
0.2
Mustard
-
-
-
-
-
-
3
-
Cod liver oil
-
-
-
-
-
4
10
14.5
Linseed
-
-
-
-
-
0.2
6
-
Tung
-
-
-
-
-
-
-
-

Fats and oils
(continued)
Fatty acids %
C18:0 Stearic
C18:1 Oleic
C18:2 Linoleic
C18:3 Linolenic
C20:0 C22:0 Arachydic - Behenic & others
Mono-
unsaturated acids <C16:1
C20:1 C22:1 Arachidonic - Erucic & others
Molecular wt.
284
282
280
278
326
226
324
Tallow
24.1
40.7
2
-
0.7
-
0.3
Lard
13
45.2
10.3
-
-
-
2.5
Butter
12
26
3
-
1.65
1.5
0.85
Coconut
2.5
6.5
2
-
-
-
0.5
Palm kernel
2
14
1
-
1.5
-
-
Palm
3.5
46
7.5
-
-
-
-
Safflower
2.2
76.4
16.2
-
-
-
-
Peanut
4.5
52
27
-
7.5
-
-
Cottonseed
2
31
44
-
-
-
2.5
Maize
2.5
40
45
-
-
-
1
Olive
2
68
12
-
0.5
-
1
Sunflower
4.2
18.7
69.4
0.3
1.4
-
-
Soy
2.5
26
51
5
7
-
-
Rapeseed/Canola
2
13.5
17
7.5
0.9
-
56.3
Mustard
1.5
39.5
12
8
-
-
36
Cod liver oil
0.5
28
-
-
-
1
42
Linseed
5
17.3
16
55
0.5
-
-
Tung
-
8
12
80
-
-
-

Oils and fats
Total
molecular weight
Density
Density
@ 50ºC
Volume
oil (ml)
Volume
methanol (ml)
Stoich. ratio
methanol : oil %
Tallow
858.54
0.895
0.88
981.18
121.52
12.4
Lard
863.73
0.92*
0.9*
959.7*
121.52
12.7
Butter
797.64
0.91
0.89
896.73
121.52
13.6
Coconut
674.51
0.926
0.91
744.57
121.52
16.3
Palm kernel
704
0.912
0.89
789.33
121.52
15.4
Palm
847.28
0.923
0.9
938.29
121.52
13
Safflower
879.1
0.927
0.91
966.44
121.52
12.6
Peanut
885.02
0.919
0.9
984.45
121.52
12.3
Cottonseed
867.38
0.918
0.9
963.76
121.52
12.6
Maize
872.81
0.923
0.9
966.57
121.52
12.6
Olive
870.65
0.923
0.9
964.17
121.52
12.6
Sunflower
877.22
0.925
0.91
969.3
121.52
12.5
Soy
882.82
0.925
0.91
975.5
121.52
12.5
Rapeseed/Canola
959.04
0.914
0.89
1072.75
121.52
11.3
Mustard
925.43
0.916
0.9
1032.85
121.52
11.8
Cod liver oil
908.81
0.929
0.91
1000.34
121.52
12.1
Linseed
872.4
0.934
0.91
954.48
121.52
12.7
Tung
873.68
0.944
0.92
945.54
121.52
12.9
* Approximate

Comparison of Feed stock for Soap Manufacture
Fatty Acid
Jatropha
Palm
Coconut
Caprylic Acid, (C8:0)
-
-
8
Capric Acid, (C10:0)
-
-
8
Lauric Acid, (C12:0)
-
-
48
Myristic Acid, (C14:0)
0.38
3.5
16.0
Palmitic Acid, (C16:0)
16.0
39.5
8.5
Palmetoleic Acid, (C16:1)
1-3.5
-
-
Stearic Acid, (C18:0)
6-7
3.5
2.5
Oleic Acid, (C18:1)
42-43.5
46
6.5
Linoleic Acid, (C18:2)
33-34.5
7.5
2.0
Linolenic Acid, (C18:3)
0.8
-
-
Production Kg/Hectare
1590
5000
2260

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